United States of America
- Centerville, city of Bibb County, Alabama
- Centerville, census-designated place in Fairfax County, Virginia
- Centerville, a town in St. Clair County, Illinois
- Centerville, the county seat of Queen Anne's County, Maryland
- Centerville, the county seat of St. Joseph County, Michigan
- Centerville, city in Wilkinson County, Mississippi