Argentina
- Partido of Bolívar, division of the province of Buenos Aires
Bolivia
- province of Bolívar, province of the department of Cochabamba
- Bolívar, capital of the homonymous province
Colombia
- Bolívar Department
- Bolivar, municipality of the department of Cauca
- Bolivar, municipality of the Santander department
- Bolivar, municipality of the department of Cauca Valley
- Ciudad Bolívar, municipality of the department of Antioquia
- Pico Simón Bolívar, together with the Pico Cristóbal Colón it is the highest point in Colombia (5,775 m)
Costa Rica
Ecuador
- Bolívar, capital of the canton of Bolívar, province of Carchi
- Canton of Bolívar, canton of the province of Carchi
- Canton of Bolívar, canton of the province of Manabí
- province of Bolívar, province of Ecuador
El Salvador
- Bolívar, municipality of El Salvador
Peru
- province of Bolívar, province of Peru
- Bolívar district, district of Peru
- Bolívar, city in the region of The Libertad and capital of the province of the same name
Spain
- Bolívar or Bolíbar (Bolibar with modern Basque spelling) - small village of the Biscay, from which the ancestors of Simón Bolívar came, and which is the origin of his surname
United States of America
- Bolivar, city in Polk County, Missouri
- Bolivar, city in Allegany County, New York
- Bolivar, Tuscarawas County village, Ohio
- Bolivar, Westmoreland County Borough, Pennsylvania
- Bolivar, city of Hardeman County, Tennessee
- Bolivar, city in Jefferson County, West Virginia
Venezuela
- State of Bolívar, one of the 25 states of Venezuela
- Pico Bolívar, the highest point in Venezuela (5,007 m)
- Cerro Bolívar, another peak in eastern Venezuela (802 m)
- Ciudad Bolívar, a city in eastern Venezuela
Other
- Bolívar, currency of Venezuela